THE TONIGHT SHOW STARRING JIMMY FALLON -- Episode 0126 -- Pictured: Douglas Gorenstein/NBC/NBCU Photo Bank)
Douglas Gorenstein/NBC/NBCU Photo Bank

Gwen Stefani and Blake Shelton are Hollywood's latest adorable couple, but they're also notable artists in their respective genres. So it was only a matter of time before the two Voice judges decided to record a song together! In comes the charming duet, "Go Ahead and Break My Heart."

The lovey-dovey track, which is now available for purchase/preview on iTunes here, finds Gwen once again stepping out of her pop/ska musical zone as she did with collaborations like "My Heart is Open" with Maroon 5.

"Go Ahead and Break My Heart" will be found on Shelton's forthcoming album, If I'm Honest, which is out May 20. The couple plan to perform the song for the first time on The Voice this week.

Watch a promo of their performance below, and click here for our roundup of the best Gwen Stefani deep cuts.